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 Environment ENS --
Environment News Service

New Test Makes Spotting Deadly Beryllium Dust Easier

LOS ALAMOS, New Mexico, September 7, 2001 (ENS) - Detecting hazardous beryllium on surfaces is now as simple as testing the acidity of a swimming pool, due to the work of scientists at the Department of Energy's Los Alamos National Laboratory in New Mexico.

Beryllium is a rare element that is extracted from the earth, refined and reduced to a very fine powder. Because of the dangers associated with inhaling beryllium dust, the Department of Energy (DOE) has adopted a limit for workplace beryllium exposure.

Los Alamos researchers Tammy Taylor and Nan Sauer have developed a test for beryllium that compares a color change to known standards, similar to the common litmus test for measuring the acidity of a water solution. The test allows real-time detection of beryllium contamination on surfaces.

The new beryllium detection technique involves wiping the surfaces of the lab with a prepared pad and then adding a solution. If the pad turns blue, beryllium is present; if it remains orange, then the surface is free of significant contamination.

swipe

Worker holds up a swipe that is free of beryllium contamination. (Photo courtesy Los Alamos National Laboratory)
Keeping workplace surfaces clean helps minimize the potential for worker exposure. People exposed to beryllium dust or fumes can develop chronic beryllium disease, an incurable lung ailment.

Taylor presented details of the new swipe detection method at the 222nd national meeting of the American Chemical Society in Chicago late last month.

Beryllium is widely used in aerospace, computer, sporting goods, electronics and in nuclear weapons applications because of its unique materials properties. The metal is lighter than aluminum, stiffer than steel, remains solid at high temperatures and can absorb large amounts of heat.

Breathing fine particulate beryllium triggers an autoimmune response in an estimated one to six percent of exposed individuals that can result in chronic beryllium disease (CBD), a debilitating and sometimes fatal disease. Currently there is no cure for CBD. The dust is generated from the handling of beryllium powder or from the grinding of beryllium ceramics.

There is no known safe level of beryllium exposure and minimal exposures to beryllium have been shown to cause chronic beryllium disease in susceptible individuals. Even household family members of individuals who work with beryllium can develop CBD from exposure to dust on a worker's clothing. So people working with beryllium must minimize exposure and establish rigorous housekeeping practices.

Taylor and Sauer realized in order to do their research efficiently and with the highest degree of safety they needed to develop a rapid test to assess beryllium contamination.

"When we began working with beryllium in our labs, we wanted to take every safety precaution because of the risks associated with beryllium work," said Taylor, who developed the beryllium swipe technique. "We wanted to develop a quick test to say whether our area was clean and it was safe to perform experiments. The beryllium swipe technique will permit beryllium workers to monitor surfaces in their work environment thoroughly on a regular basis at minimal expense and without delays or excessive lost work time due to waiting for test results."

clubs

Beryllium copper and beryllium nickel golf clubs (Photo courtesy )
The present method for detecting beryllium in the workplace is costly and time consuming. It may take days or weeks to obtain results of laboratory analysis. In many cases work cannot be performed until results come back indicating beryllium levels are below the acceptable surface contamination limit.

Taylor's beryllium colorimetric test is not meant to replace the existing method that can quantify the amount of beryllium on a surface, but to allow a worker to get a quick, qualitative result indicating the effectiveness of housekeeping efforts and contamination control. The new method is expected to cut down on the number of samples sent for costly quantitative analysis.

Gary Whitney, an industrial hygienist at Los Alamos who conducts beryllium monitoring, said, "This test has the potential to give us preliminary information very quickly and at low cost. We are in the process of seeing if this could be developed into a more quantitative method and not just a quick screening method. I have conducted some preliminary side-by-side tests using Taylor's technique and the quantitative analytical technique. The initial results look promising."

Preparing the pads and performing the detection test for beryllium are simple tasks. The pads are soaked in two solutions, dried and then used to wipe the potentially contaminated surface. After wiping, the pad is treated with another solution and formation of a blue color indicates beryllium. The whole process takes less than an hour and the materials for each test cost less than a dollar.

"We've conducted this test with a variety of potential interferences like cutting fluids [used in machining metals], mineral oil, common household cleansers and dust to see if they interact with the beryllium and give a false negative," said Taylor. "We've also done the test with other metals that may be present in the machine shops or at beryllium contaminated sites to make sure that the pads don't register false positives."

The beryllium test developed at Los Alamos builds upon an earlier beryllium measuring technique developed by Russian scientists.

electronics

Electronics components containing beryllium (Photo courtesy Leader Tech)
Department of Energy rules on beryllium have established surface contamination limits for beryllium work areas and equipment. The detection technique developed by Taylor is sensitive enough to allow detection of beryllium on surfaces within these limits.

The test may also save the government money that might otherwise have to be paid to workers exposed to beryllium under The Energy Employees Occupational Illness Compensation Program Act signed into law last year. The program, established after the Energy Department accepted responsibility for exposing thousands of workers to radioactive materials during the Cold War, covers workers who came in contact with beryllium.

The program offers one time $150,000 payments and lifetime medical coverage to nuclear workers and others made ill by the government's nuclear weapons program. Any workers who developed chronic beryllium disease after working at any Energy Department sites where beryllium was used will get coverage if they died or were disabled. Those found to have beryllium sensitivity will be covered for regular medical screenings, but not for the $150,000 pay out.

Eligible to apply for benefits are workers at Department of Energy facilities; atomic weapons employers involved in the production of nuclear weapons under contract to the Energy Department or its predecessor agencies; and beryllium vendors, companies that sold beryllium metal or parts to the Department of Energy or its predecessor agencies.

Los Alamos National Laboratory is operated by the University of California for the U.S. Department of Energy's National Nuclear Security Administration.

DOE Chronic Beryllium Disease Prevention Program: http://www.tis.eh.doe.gov/be/index.html-ssi

DOE Office of Worker Advocacy: http://www.eh.doe.gov/advocacy/

Beryllium Support Group: http://www.dimensional.com/~mhj/index.html


 


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